Enhanced Magnetic Properties Through Alignment of Non-Magnetic Constituents

ABSTRACT

The present invention relates to a method of producing permanent magnets free of rare-earth metals. Specifically the type of magnets produced by the present invention are rare-earth free magnets based on iron. More specifically, the magnets of the present invention are of the class hexaferrites. The present invention further relates to magnets produced by the method of the invention, which are highly aligned magnets with improved magnetic properties compared to commercially available analogues.

SUMMARY

The present invention relates to a way of making permanent magnets free of rare-earth metals. Specifically the type of magnets produced by the present invention are rare-earth free magnets based on iron. More specifically, the magnets of the present invention are of the class hexaferrites.

The inventors have discovered a new synthesis route, which allows for the manufacture of an iron-based non-ferromagnetic precursor, which can be converted into hexaferrite permanent magnets. The thus formed non-ferromagnetic precursor, which comprises a large fraction of crystallites having a platelet or needle morphology, can be transformed into a permanent magnet, either in a one-step process by way of spark plasma sintering (SPS) or in a two-step process by first compacting a crystalline powder into a pellet, and subsequently calcination. Taking advantage of the anisotropic shape of the precursor, the inventors demonstrate that it is possible to align the precursor and obtain a crystallographic preferred orientation, which facilitates alignment of the crystallites constituting the hexaferrite permanent magnet and allows alignment of the individual atomic magnetic dipole moments upon formation of the hexaferrite permanent magnet.

Equally important to the anisotropic morphology is also the non-ferromagnetic nature of the precursor. Since the precursor is non-ferromagnetic the magnetic domain short-circuiting is eliminated during the compaction step of the hexaferrite permanent magnet, which would otherwise require heating above the Curie temperature of the precursor, or alternatively application of large magnetic fields to break the ferromagnetic interaction. Both of these processes are undesirable in terms of industrial scale-up, and so it is beneficial to eliminate these.

Consequently, by utilizing the non-ferromagnetic anisotropic precursor of the present invention, it is possible to produce rare-earth free magnets with improved magnetic properties compared to commercially available equivalents in an industrially relevant scale. Additionally, the non-ferromagnetic anisotropic precursor employs significantly fewer process steps compared to conventional synthesis of rare-earth free magnets.

DETAILED DISCLOSURE

On aspect of the invention relates to a non-ferromagnetic strontium hexaferrite precursor with a concentration of more than 15% by weight of anisotropic crystalline materials of the group consisting of six-line ferrihydrite (SLF), α-Fe2O3, and/or α-FeOOH, each with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm.

Non-ferromagnetic: By this is understood a chemical entity having unpaired electrons, and where no permanent magnetism is observed (i.e., the magnetization is approximately zero under zero applied external field) within the temperature range relevant for the present disclosure, preferably at room temperature. The phrases “non-ferromagnetic”, and “non-magnetic” may be used interchangeably herein.

Precursor: By this is understood a chemical entity which has the potential of being transformed by technical manipulation into an envisioned product, in this case an iron-containing precursor is transformed into the envisioned product which is a strontium hexaferrite permanent magnet. The phrases “non-ferromagnetic precursor”, “non-magnetic precursor”, and “precursor” may be used interchangeably herein.

Aspect ratio: By this is understood the ratio between the length (A direction) of a crystal of the precursor and the height (C direction) of the same crystal (see also FIGS. 2 a and 2 b ). This difference between A and C is what gives the precursor its unique properties in terms of facilitating alignment of the crystallites in the final magnet.

Anisotropic crystallite: By this is understood that the crystallites are not spherical, i.e., the crystallites are rather platelet, plate-like shaped, needle or needle-like shaped so that when compressed, a substantial fraction of the crystallites, such as all the crystallites will align in the same direction due to the difference in aspect ratio (see also Aspect ratio above).

The crystallite aspect ratio of the precursor material as disclosed herein is defined by A/C, and should in one embodiment of the present disclosure be larger than 2. The aspect ratio is crucial to the present disclosure, which relies on the preferred orientation of precursors in the synthesis of hexaferrite permanent magnets, preferably strontium hexaferrite permanent magnets.

In one embodiment of the present disclosure the non-magnetic precursor has an average aspect ratio defined by A/C≥2, such as A/C≥5, such as A/C≥10, such as A/C≥25, such as A/C≥50, such as A/C≥100, such as A/C≥1000.

In one embodiment of the present disclosure, the non-magnetic precursor comprises crystallites having a platelet, or platelet-like morphology.

In one embodiment of the present disclosure, the non-magnetic precursor comprises crystallites having a needle, or needle-like morphology.

Much like a deck of playing cards, when dropped on the floor, most of the cards will lay flat on top of each other, while only very few can be expected to land on their narrow side. Likewise for needles if needles are dropped to the floor the long part of the needle will lay flat parallel with the floor, it is very unlikely that the needle will be standing up vertically.

The larger the crystallite aspect ratio of the precursor of the present disclosure (see FIGS. 2 a and 2 b ), the higher is the probability for the crystallites to stack in a preferred orientation, which in turn facilitates improved magnetic properties.

In one embodiment of the present disclosure, the average aspect ratio A/C≥2.

In one embodiment of the present disclosure, the average aspect ratio A/C≥5.

In one embodiment of the present disclosure, the average aspect ratio A/C≥10.

In one embodiment of the present disclosure, the average aspect ratio A/C≥25.

In one embodiment of the present disclosure, the average aspect ratio A/C≥50.

In one embodiment of the present disclosure, the average aspect ratio A/C≥100.

In one embodiment of the present disclosure, the average aspect ratio A/C≥1000.

In one embodiment of the present disclosure, C is ranging from 2-200 nm, such as from 200-170 nm, such as from 170-140 nm, such as from 140-110 nm, such as from 110-80 nm, such as from 80-50 nm, such as from 50-30 nm, such as from 30-20 nm, such as from 20-15 nm, such as from 15-10 nm, such as from 10-2 nm.

In one embodiment of the present disclosure, A is ranging from 4-2000 nm, such as from 2000-1500 nm, such as from 1500-1000 nm, such as from 1000-500 nm, such as from 500-250 nm, such as from 250-125 nm, such as from 125-50 nm, such as from 50-40 nm, such as from 40-30 nm, such as from 30-20 nm, such as from 20-10 nm, such as from 10-4 nm.

In one aspect of the invention, the precursor has a concentration of anisotropic crystalline materials making up 100% by weight, such as 100-15 wt %, such as 95-85 wt %, such as 85-75 wt %, such as 75-65 wt %, such as 65-55 wt %, such as 55-45 wt %, such as 45-35 wt %, such as 35-25 wt %, such as 25-15 wt %.

In one embodiment, the anisotropic crystalline material of said precursor is largely or consisting essentially of α-Fe₂O₃.

In one embodiment, the anisotropic crystalline material of said precursor is largely or consisting essentially of six-line ferrihydrite (SLF).

In one embodiment, the anisotropic crystalline material of said precursor is largely or consisting essentially of α-FeOOH.

In one embodiment, the anisotropic crystalline material of said precursor is a mixture of goethite (α-FeOOH) and hematite (α-Fe₂O₃).

In one embodiment, the mixture of goethite (α-FeOOH) and hematite (α-Fe₂O₃) is provided in a ratio ranging from 100/0 to 0/100, respectively. In one embodiment, the Goethite (α-FeOOH)/Hematite (α-Fe₂O₃) ratio is provided as any one of 100/0, 90/10, 80/20, 70/30, 60/40, 50/50, 40/60, 30/70, 20/80, 10/90, and 0/100, respectively.

In one embodiment, the mixture of goethite (α-FeOOH) and hematite (α-Fe₂O₃) is provided in a composition of 100% hematite, 75% hematite and 25% goethite, 50% hematite and 50% goethite, 25% hematite and 75% goethite, and 100% goethite.

In a further embodiment of the present invention, the non-ferromagnetic strontium hexaferrite precursor further comprises one or more sources of metals such as Calcium (Ca), Strontium (Sr), Barium (Ba) Magnesium (Mg), Manganese (Mn), Iron (Fe), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), and Lanthanum (La).

The non-ferromagnetic strontium hexaferrite precursors of the present invention are prepared under autogenous reaction conditions at a maximum temperature of 200° C. as exemplified in Example 1. By this approach, a composition is produced which has an amount of platelet shaped six-line ferrihydrite (SLF) crystallites of at least 15 wt %. The minimum percentage of 15 wt % is obtained when conducting the reaction at the lowest temperature of 100° C., while the amount increases upon elevating the temperature. At 150° C. the amount is 38 wt % and at 200° C. it has decreased to 30 wt %. It is thus possible to tune the amount of SLF by controlling the temperature of the reaction. It is also envisioned that for a fixed temperature, control of the reaction time could be used to tune the amount of SLF in the final composition. The same arguments hold for a composition comprising anisotropic Hematite or Goethite.

One aspect of the present invention is a method of producing a non-ferromagnetic precursor, comprising the steps of:

-   -   a. mixing salts of Fe³⁺ with a strong alkaline solution to form         a gel,     -   b. transferring said gel to an autoclave, and sealing said         autoclave,     -   c. placing said autoclave at a temperature ranging from 200-150°         C., such as from 150-100° C., such as 100° C. for more than 1 h,         such as 1-2 hours, such as 2-4 hours, such as 4-8 hours, such as         8-24 hours, under autogenous pressure, and     -   d. isolating the formed anisotropic crystalline non-magnetic         precursor material.

One embodiment of the present invention is the method as defined above, wherein the alkaline solution is made by dissolving NaOH or KOH in water.

One embodiment of the present invention is the method as defined above, wherein the reaction temperature is 200° C.

One embodiment of the present invention is the method as defined above, wherein the reaction temperature is 150° C.

One embodiment of the present invention is the method as defined above, wherein the reaction temperature is 100° C.

One embodiment of the present invention is the method as defined above, wherein the reaction temperature is in a range of 100-200° C., such as 100-110° C., such as 110-120° C., such as 120-130° C., such as 130-140° C., such as 140-150° C., such as 150-160° C., such as 160-170° C., such as 170-180° C., such as 180-190° C., such as 190-200° C.

One embodiment of the present invention is the method as defined above, wherein the reaction time is 1 hour.

One embodiment of the present invention is the method as defined above, wherein the reaction time is 1-2 hours.

One embodiment of the present invention is the method as defined above, wherein the reaction time is 2-4 hours.

One embodiment of the present invention is the method as defined above, wherein the reaction time is 4-8 hours.

One embodiment of the present invention is the method as defined above, wherein the reaction time is 8-24 hours.

One embodiment of the present invention is the method as defined above, wherein the reaction time is more than 1 hour, such as in a range of 1-24 hours, such as 1-2 hours, such as 2-4 hours, such as 4-8 hours, such as 8-24 hours.

A further embodiment of the present invention is the method as defined above, wherein a source of divalent metal ion such as Calcium (Ca), Strontium (Sr), Barium (Ba) Magnesium (Mg), Manganese (Mn), Iron (Fe), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), and trivalent Lanthanum (La) may optionally be added during step a.

In one embodiment, the optionally added metal is Strontium (Sr).

In one embodiment, the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is largely or consisting essentially of α-Fe₂O₃, and the Fe/Sr ratio is 12.

In one embodiment, the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is largely or consisting essentially of six-line ferrihydrite (SLF), and the Fe/Sr ratio is 8.

In one embodiment, the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is largely or consisting essentially of α-FeOOH, and the Fe/Sr ratio is 12.

In one embodiment, the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is largely or consisting essentially of α-FeOOH, and the Fe/Sr ratio is 10.

In one embodiment, the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is largely or consisting essentially of α-FeOOH, and the Fe/Sr ratio is in a range of 10 to 12.

In one embodiment, the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is a mixture of goethite (α-FeOOH) and hematite (α-Fe₂O₃), and the Fe/Sr ratio is 12.

In one embodiment, the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is a mixture of goethite (α-FeOOH) and hematite (α-Fe₂O₃), and the Fe/Sr ratio is 10.

In one embodiment, the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is a mixture of goethite (α-FeOOH) and hematite (α-Fe₂O₃), and the Fe/Sr ratio is in a range of 10 to 12.

Non-Ferromagnetic Strontium Hexaferrite Precursor Comprising Six-Line Ferrihydrite (SLF)

In one embodiment of the present invention, the anisotropic crystalline material of the precursor is six-line ferrihydrite (SLF).

One embodiment of the present invention is a method of producing a non-ferromagnetic strontium hexaferrite precursor comprising six-line ferrihydrite (SLF), the method comprising the steps of:

-   -   a. mixing salts of Fe³⁺ and Sr²⁺ with a strong alkaline solution         to form a gel,     -   b. transferring said gel to an autoclave, and sealing said         autoclave,     -   c. placing said autoclave at a temperature ranging from         200-100° C. for more than 1 hour under autogenous pressure, and     -   d. isolating the formed anisotropic crystalline         non-ferromagnetic strontium hexaferrite precursor material         comprising six-line ferrihydrite (SLF).

In one embodiment of the method as described above, the alkaline solution is made by dissolving NaOH in water.

In one embodiment of the method as described above, the alkaline solution comprise 8 M NaOH solution.

In one embodiment of the method as described above, the alkaline solution is added by slow addition, such as drop-wise addition.

In one embodiment of the method as described above, the reaction time under autogenous pressure is 5 hours.

In one embodiment of the method as described above, the reaction temperature is in a range of 100-200° C., such as 100-110° C., such as 110-120° C., such as 120-130° C., such as 130-140° C., such as 140-150° C., such as 150-160° C., such as 160-170° C., such as 170-180° C., such as 180-190° C., such as 190-200° C.

In one embodiment of the method as described above, the reaction temperature is 100° C.

In one embodiment of the method as described above, the reaction temperature is 150° C.

In one embodiment of the method as described above, the reaction temperature is 200° C.

In one embodiment of the method as described above, the salts of Fe³⁺ and Sr²⁺ in the above method are mixed in an Fe/Sr ratio of 8.

In one embodiment of the method as described above, the salts used in the above method are nitrate (NO₃)⁻ salts.

In one embodiment of the method as described above, the salts of Fe³⁺ are provided in a 3 M solution of Fe(NO₃)₃·9H₂O.

In one embodiment of the method as described above, the salts of Sr²⁺ are provided in a 0.75 M solution of Sr(NO₃)₂.

In one embodiment of the method as described above, the isolated non-ferromagnetic strontium hexaferrite precursor material comprises at least approximately 15 wt % six-line ferrihydrite (SLF) crystallites having a platelet or platelet-like morphology with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm.

One embodiment of the present disclosure is a non-ferromagnetic strontium hexaferrite precursor material comprising at least approximately 15 wt % six-line ferrihydrite (SLF) crystallites having a platelet or platelet-like morphology with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm obtainable by the method as described above.

Non-Ferromagnetic Strontium Hexaferrite Precursor Comprising Hematite (α-Fe₂O₃)

In one embodiment of the present invention, the anisotropic crystalline material of the precursor is Hematite (α-Fe₂O₃).

One embodiment of the present invention is a method of producing a non-ferromagnetic strontium hexaferrite precursor comprising Hematite (α-Fe₂O₃), the method comprising the steps of:

-   -   a. mixing salts of Fe³⁺ with a strong alkaline solution to form         a mixture comprising a dark red precipitate,     -   b. transferring said mixture to an autoclave, and sealing said         autoclave,     -   c. placing said autoclave at a temperature ranging from         200-100° C. for more than 1 hour under autogenous pressure,     -   d. isolating the formed anisotropic crystalline non-magnetic         precursor material, and     -   e. adding a source of Strontium (Sr) to the isolated material to         obtain the non-ferromagnetic strontium hexaferrite precursor         comprising Hematite (α-Fe₂O₃).

In one embodiment of the method as described above, the isolating step d of the method comprises washing the formed anisotropic crystalline non-magnetic precursor material with water to neutral pH (pH of 7), followed by washing with ethanol and drying at 85° C. until dry.

In one embodiment of the method as described above, the alkaline solution is made by dissolving NaOH in water.

In one embodiment of the method as described above, the alkaline solution comprise 8 M NaOH solution.

In one embodiment of the method as described above, the reaction temperature is 160° C.

In one embodiment of the method as described above, the reaction time under autogenous pressure is 2 hours.

In one embodiment of the method as described above, the salt of Fe³⁺ is provided in a 2 M solution of FeCl₃·6H₂O.

In one embodiment of the method as described above, the method comprise an Fe/OH molar ratio of 4.

In one embodiment of the method as described above, the source of Strontium (Sr) is selected from SrCO₃ and Sr(OH)₂.

In one embodiment of the method as described above, the method comprise an Fe/Sr molar ratio of 12.

In one embodiment of the method as described above, the isolated non-ferromagnetic strontium hexaferrite precursor material comprises at least approximately 15 wt % Hematite (α-Fe₂O₃) crystallites having a platelet or platelet-like morphology with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm.

One embodiment of the present disclosure is a non-ferromagnetic strontium hexaferrite precursor material comprising at least approximately 15 wt % Hematite (α-Fe₂O₃) crystallites having a platelet or platelet-like morphology with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm obtainable by the method as described above.

Non-Ferromagnetic Strontium Hexaferrite Precursor Comprising Goethite (α-FeOOH)

In one embodiment of the present invention, the anisotropic crystalline material of the precursor is Goethite (α-FeOOH).

One embodiment of the present invention is a method of producing a non-ferromagnetic strontium hexaferrite precursor comprising Goethite (α-FeOOH), the method comprising the steps of:

-   -   a. mixing salts of Fe³⁺ with a strong alkaline solution to form         a mixture comprising a dark red precipitate,     -   b. transferring said mixture to an autoclave, and sealing said         autoclave,     -   c. placing said autoclave at a temperature ranging from         200-100° C. for more than 1 hour under autogenous pressure,     -   d. isolating the formed anisotropic crystalline non-magnetic         precursor material, and     -   e. adding a source of Strontium (Sr) to the isolated material to         obtain the non-ferromagnetic strontium hexaferrite precursor         comprising Goethite (α-FeOOH).

In one embodiment of the method as described above, the pH of the mixture comprising a dark red precipitate is maintained at 11 when transferring said mixture to an autoclave.

In one embodiment of the method as described above, the isolating step d of the method comprises washing the formed anisotropic crystalline non-magnetic precursor material with water to neutral pH (pH of 7), followed by washing with ethanol and drying at 85° C. until dry.

In one embodiment of the method as described above, the source of Strontium (Sr) is selected from SrCO₃.

In one embodiment of the method as described above, the method comprise an Fe/Sr molar ratio of 12.

In one embodiment of the method as described above, the method comprise an Fe/Sr molar ratio of 10.

In one embodiment of the method as described above, the method comprise an Fe/Sr molar ratio ranging from 10 to 12.

In one embodiment of the method as described above, the alkaline solution is made by dissolving NaOH in water.

In one embodiment of the method as described above, the alkaline solution comprise 8 M NaOH solution.

In one embodiment of the method as described above, the salts of Fe³⁺ are provided in a 1 M solution of Fe(NO₃)₃·9H₂O.

In one embodiment of the method as described above, base was added in an amount to obtain an [OH⁻]/[NO₃ ⁻] ratio of 1.33.

In one embodiment of the method as described above, the reaction temperature is 100° C.

In one embodiment of the method as described above, the reaction time under autogenous pressure is 10 hours.

In one embodiment of the method as described above, the isolated non-ferromagnetic strontium hexaferrite precursor material comprises at least approximately 15 wt % Goethite (α-FeOOH) crystallites having a needle or needle-like morphology with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm.

One embodiment of the present disclosure is a non-ferromagnetic strontium hexaferrite precursor material comprising at least approximately 15 wt % Goethite (α-FeOOH) crystallites having a needle or needle-like morphology with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm obtainable by the method as described above.

Strontium Hexaferrite Permanent Magnets

The non-ferromagnetic strontium hexaferrite precursors obtained in Example 1 may be converted into strontium hexaferrite permanent magnets either in a one-step process by way of spark plasma sintering (SPS) as in Example 4, or in a two-step process by first compacting into a powder, and subsequently calcination as in Example 5. Either way, the result is a structurally highly aligned permanent magnet evidenced by the X-ray diffraction patterns and associated Rietveld analysis found in Examples 3 and 4.

One aspect of the present invention relates to the non-magnetic precursor for use in formation of a strontium hexaferrite permanent magnet.

One embodiment of the present invention is the method of producing a strontium hexaferrite permanent magnet as defined herein, wherein the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is largely or consisting essentially of α-Fe₂O₃.

One embodiment of the present invention is the method of producing a strontium hexaferrite permanent magnet as defined herein, wherein the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is largely or consisting essentially of six-line ferrihydrite (SLF).

One embodiment of the present invention is the method of producing a strontium hexaferrite permanent magnet as defined herein, wherein the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is largely or consisting essentially of α-FeOOH.

One embodiment of the present invention is the method of producing a strontium hexaferrite permanent magnet as defined herein, wherein the anisotropic crystalline material of said non-ferromagnetic strontium hexaferrite precursor is a mixture of Goethite (α-FeOOH) and Hematite (α-Fe₂O₃).

In one embodiment, the mixture of Goethite (α-FeOOH) and Hematite (α-Fe₂O₃) is provided in a ratio ranging from 100/0 to 0/100, respectively. In one embodiment, the Goethite (α-FeOOH)/Hematite (α-Fe₂O₃) ratio is provided as any one of 100/0, 90/10, 80/20, 70/30, 60/40, 50/50, 40/60, 30/70, 20/80, 10/90, and 0/100, respectively.

In one embodiment, the mixture is provided in a composition of 100% hematite, 75% hematite and 25% goethite, 50% hematite and 50% goethite, 25% hematite and 75% goethite, and 100% goethite.

Spark Plasma Sintering (SPS)

One aspect of the present invention is a method of producing a strontium hexaferrite permanent magnet comprising the steps of:

-   -   a. providing a non-ferromagnetic strontium hexaferrite precursor         as defined herein,     -   b. compacting said precursor at a temperature between         700-1000° C. by spark plasma sintering (SPS) in the absence of         any applied magnetic field, thereby inducing a phase change, and     -   c. isolating the thus formed strontium hexaferrite permanent         magnet.

In one embodiment of the above method, the temperature is set at 750° C. and the pressure applied was 100 MPa during the sintering process, which was completed after 8 minutes.

Cold Compaction and Calcination

Another aspect of the present invention is a method of producing a strontium hexaferrite permanent magnet comprising the steps of:

-   -   a. providing a non-ferromagnetic strontium hexaferrite precursor         as defined herein,     -   b. compacting said precursor by the application of pressure,     -   c. calcining said compacted precursor at a temperature between         700-1220° C. in the absence of any applied magnetic field,         thereby inducing a phase change, and     -   d. isolating the thus formed strontium hexaferrite permanent         magnet.

In one embodiment of the above method, the pressure applied in the compacting step was 700 MPa for 5 minutes.

In one embodiment of the above method, the compacted precursor was sintered in a temperature between 700 to 1220° C. In one embodiment, the temperature was between 700 to 800° C. In one embodiment, the temperature was between 800 to 900° C. In one embodiment, the temperature was between 900 to 1000° C. In one embodiment, the temperature was between 1000 to 1100° C. In one embodiment, the temperature was between 1100 to 1220° C.

In one embodiment of the above method, the sintering temperature was 750° C.

In one embodiment of the above method, the sintering temperature was 900° C.

In one embodiment of the above method, the sintering temperature was 1050° C.

In one embodiment of the above method, the sintering took place for 2 hours. In one embodiment, the samples were held in an Al₂O₃ crucible during sintering.

Characterization of Highly Aligned Strontium Hexaferrite Permanent Magnets

X-ray powder diffraction is a technique which is highly sensitive to the crystal structure and the spatial orientation of crystallites in a sample.

The analysis of a powder diffractogram obtained from X-ray powder diffraction is based on the Braggs law of diffraction, which is given by the following relation:

nλ=2d sin(θ)

Where n is an integer, λ is the X-ray wavelength used for the measurement, θ is the angle of incidence between the X-ray beam and the sample, and d is the interplaner spacing between crystal planes defined by the Miller indices h, k, and l, which relates to the crystallographic a, b, and c parameters of the crystal unit cell. Thus if a sample contains any crystallites in a preferred orientation, the reflections presented as (hkl) will not be uniformly found in the powder diffraction pattern. Instead, reflections of predominantly (h00), (0k0), or (00l) will be found, which indicates preferred orientation along the crystallographic a-, b-, or c-direction respectively.

As evidenced in Examples 4, 5, and 8, the X-ray diffraction patterns of the synthesized hexaferrite permanent magnets are characterized by having a high degree of preferred orientation along the crystallographic (00l) reflection, with these reflections being largely more intense than other reflections.

One embodiment of the present invention is a strontium hexaferrite permanent magnet as defined herein, further comprising pronounced Bragg reflections along the (00l) reflection, as evidenced by powder X-ray diffraction obtained in reflection mode using Co-Kα radiation.

As already briefly explained, a uniform or non-aligned sample will be characterized by Bragg reflection intensities, stemming from randomly oriented crystallites for all Miller indices. The extent of alignment may as such be evaluated by comparing the relative intensities of orthogonal Bragg reflections, e.g., the comparison of a (00l) reflection which corresponds to a crystallite lying flat on its face, and a (hk0) reflection which corresponds to a crystallite standing on its side.

One embodiment of the present invention is a strontium hexaferrite permanent magnet comprising highly aligned strontium hexaferrite, characterized by its most intense Bragg reflections being the (006), (008), (107) and (0014) reflections, and wherein the (008)/[(110+008)] integrated intensity ratio is at least 0.5 as obtained by X-ray powder diffraction using Co-Kα radiation. In one embodiment, the (008)/[(110+008)] integrated intensity ratio is at least 0.6, such as at least 0.7, such as at least 0.8, such as at least 0.9, such as at least 0.95.

One embodiment of the present invention is the strontium hexaferrite permanent magnet as defined herein, further comprising an X-ray powder diffraction pattern with characteristic peaks expressed in 2-theta angle (°) for (006) at 2θ=26.9°±0.2°, (110) at 2θ=35.4°±0.2°, (008) at 2θ=36.3°±0.2°, (107) at 2θ=37.7°±0.2° and (0014) at 2θ=65.8°±0.2° as obtained using Co-Kα radiation.

One embodiment of the present invention is the strontium hexaferrite permanent magnet as defined herein, with a powder X-ray pattern substantially similar to FIG. 9 .

This alignment effect originates from the crystallite anisotropy of the utilized precursors, as there are numerous examples in prior art of producing hexaferrite permanent magnets from isotropic precursors, to the result that no alignment is observed in the final product.

To have predominantly all the crystallites in a magnetic sample aligned in the same direction is also to have the magnet moments of said sample aligned in the same direction. Figuratively speaking, this is equal to aligning all the magnetic field lines of small individual magnets in the same direction to achieve a synergistic effect and generate a larger unidirectional magnetic field. Thus magnets constructed in this way may possess superior magnetic properties compared to non-aligned versions of the same magnets, as evidenced in Examples 5, 6 and 8.

The standard of evaluating magnetic properties in materials is to examine the hysteretic behaviour of a magnet (see FIG. 1 ). Key parameters that govern the macroscopic magnetic properties of materials are remanence magnetization (M_(r)), saturation magnetization (M_(s)), coercive field (H_(c)), and maximum energy product (BH)_(max), all of which can be extracted from the magnetic hysteresis loop.

When measuring magnetic hysteresis, a sample is subjected to an external magnetic field, which is increased from zero and up. The magnetization of the sample will then grow as the external magnetic field is increased. When the magnetization of the sample no longer increases, despite the application of larger magnetic fields, the magnetization is said to have saturated. This value is called saturation magnetization (M_(s)). The external magnetic field is then decreased back down to zero to demagnetize the sample. This causes the magnetization to decrease to a certain extent. At zero applied field (i.e., H=0) if the magnetization is non-zero, this value will be equivalent to the remanence magnetization (M_(r)). The sign of the external field is changed, and the field is increased, figuratively speaking, in the opposite direction. Since the magnetization at zero applied field of a magnet is non-zero, a negative field must be applied to bring the magnetization to zero. The value of this field is called the coercive field (H_(c)).

The alignment of moments in a sample will also impact the shape of the magnetic hysteresis curve as evidenced in FIG. 1 . A highly aligned magnet will have a very square hysteresis curve where magnetization and demagnetization events occur very abruptly upon reaching the coercive field value. If the sample is less aligned, the hysteresis loop will be more smooth in its shape. Likewise the magnetization and demagnetization events will be more gradual. The maximum energy product (BH)_(max) is strongly influenced by the shape of the hysteresis loop. Consequently a high degree of squareness as defined by M_(r)/M_(c) is favored for increasing (BH)_(max).

One embodiment of the present invention is the strontium hexaferrite permanent magnet as defined herein, further comprising a hysteretic squareness ratio (M_(r)/M_(c)) which is between 0.65 and 1.0, such as between 0.70 and 1.0, such as between 0.75 and 1.0, such as between 0.80 and 1.0, such as between 0.85 and 1.0, such as between 0.95 and 1.0.

One aspect of the present invention is the strontium hexaferrite permanent magnet as defined herein, further comprising a hysteretic squareness ratio (M_(r)/M_(s)) is between 0.95 and 1.0.

One embodiment of the present invention is the strontium hexaferrite permanent magnet as defined herein, further comprising a hysteretic squareness ratio (M_(r)/M_(s)) is between 0.85 and 1.0.

One embodiment of the present invention is the strontium hexaferrite permanent magnet as defined herein, further comprising a hysteretic squareness ratio (M_(r)/M_(s)) is between 0.80 and 1.0.

One embodiment of the present invention is the strontium hexaferrite permanent magnet as defined herein, further comprising a hysteretic squareness ratio (M_(r)/M_(s)) is between 0.75 and 1.0.

One embodiment of the present invention is the strontium hexaferrite permanent magnet as defined herein, further comprising a hysteretic squareness ratio (M_(r)/M_(s)) is between 0.70 and 1.0.

One embodiment of the present invention is the strontium hexaferrite permanent magnet as defined herein, further comprising a hysteretic squareness ratio (M_(r)/M_(s)) is between 0.65 and 1.0.

As a result of the enhanced magnetic properties obtained by the use of anisotropic non-magnetic precursors, the highly aligned strontium hexaferrite permanent magnets of the present disclosure demonstrate a broad and useful potential use in replacement of other ferrite materials or Nd₂Fe₁₄B NIB rare-earth magnets.

One embodiment of the present invention is the use of the aligned permanent magnets as defined herein as a magnetic component in a device.

In a further embodiment of the present disclosure, the device as defined herein is any one of:

-   -   a. storage devices,     -   b. generators,     -   c. stators in electric motors and/or electric generators     -   d. audio devices,     -   e. magnetic imaging scanners,     -   f. magnetic brakes,     -   g. linear motors,     -   h. electrodynamic bearings, or     -   i. magnetic toys.

DESCRIPTION OF FIGURES

FIG. 1 : standard magnetic M versus H hysteresis loop of A) a non-aligned magnet and B) a highly aligned magnet. M_(s), M_(r), and H_(c) are indicated on the figures

FIG. 2 : A) schematic representation of the platelet shaped crystallites of the non-magnet precursor, and B) schematic representation of the needle shaped crystallites of the non-magnetic precursor. The A and C lengths are indicated by arrows.

FIG. 3 : powder X-ray diffraction pattern of the non-magnetic precursors as prepared according to Example 1. The graph also shows the results of the Rietveld analysis performed according to the specification of Example 1. Bragg peak indicators of each constituent of the Rietveld analysis are shown and marked with arrows.

FIG. 4 : TEM images of the non-magnetic precursors prepared according to Example 1 at a) 100° C., b) 150° C., and c) 200° C.

FIG. 5 : powder X-ray diffraction pattern of the non-magnetic Hematite precursor as prepared from FeCl₃·6H₂O according to Example 2.

FIG. 6 : HR-TEM image showing platy morphology of hematite particles. Some crystallites are tilted, which causes them to appear darker. Pale Goethite needles are also observed in the TEM image.

FIG. 7 : Powder X-Ray diffraction pattern of the non-magnetic Goethite precursor as prepared according to Example 3. The graph also shows the results of the Rietveld analysis performed according to the specification of Example 3. Bragg peak indicators are shown under the diffraction pattern.

FIG. 8 : TEM image of the non-magnetic precursors α-FeOOH prepared according to Example 3 at 100° C. for 12 hours

FIG. 9 : powder X-ray diffraction pattern of the hexaferrite permanent magnet labelled SPS-3 obtained by SPS according to Example 4 with indicators of relevant Bragg reflections. The graph also shows the results of the Rietveld analysis performed according to the specification of Example 4. Bragg peak indicators are shown under the diffraction pattern.

FIG. 10 : powder X-ray diffraction pattern of the hexaferrite permanent magnets obtained by compacting and subsequent calcination according to Example 5 with indicators of relevant Bragg reflections. The graph also shows the results of the Rietveld analysis performed according to the specification of Example 5. Bragg peak indicators are shown under each diffraction pattern. The top and bottom samples differ only in their non-magnetic precursor production temperature. The permanent strontium hexaferrite magnet obtained by either way has the same relevant Bragg reflections and Bragg peak indicators.

FIG. 11 : magnetic hysteresis loops of the hexaferrite permanent magnets prepared by SPS according to Example 4, labelled SPS-1, SPS-2 and SPS-3, with a zoom on M_(r) and H_(c) region.

FIG. 12 : magnetic hysteresis loops of the hexaferrite permanent magnets prepared by compaction and subsequent calcination according to Example 5.

FIG. 13 : powder X-ray diffraction pattern of the hexaferrite permanent magnets obtained by compacting and subsequent calcination according to Example 8 with indicators of relevant Bragg reflections. The graph also shows the results of the Rietveld analysis performed according to the specification of Example 8. Bragg peak indicators of each constituent of the precursor are shown under each diffraction pattern.

FIG. 14 : magnetic hysteresis loops of the hexaferrite permanent magnets prepared by compaction and subsequent calcination according to Example 8 with a zoom on the M_(r) and H_(c) region. A) comparison of magnetic hysteresis for all samples of Example 8 produced by either dry mixing (DM) or wet mixing (WM) and compacted at either low pressure (220 MPa) or high pressure (870 MPa). B) comparison of magnetic hysteresis for an aligned hexaferrite sample (WM 870 MPa) and a hexaferrite sample with random orientation.

EXAMPLES Example 1: Preparation and Structural Characterization of Non-Ferromagnetic Strontium Hexaferrite Precursor Comprising Anisotropic Crystallites of Six-Line Ferrihydrite (SLF) Precursor to be Used for Subsequent Production of Strontium Hexaferrite Permanent Magnets

A solution of 3 M Fe(NO₃)₃·9H_(2pl O and) 0.75 M Sr(NO₃)₂ in a molar ratio of 8:1, respectively, was co-precipitated by the slow addition of 8 M NaOH to form a gel. Following complete addition of NaOH, the gel was allowed to stir for approximately 3 hours. The gel was then transferred to a 175 ml teflon-lined steel autoclave and placed inside an oven operating ata temperature of 200° C., 150° C., or 100° C. for 5 hours. The thus obtained samples were identified as SLF-200, SLF-150 and SLF-100 according to the synthesis temperature.

The precursors were examined by X-ray powder diffraction (Rigaku SmartLab diffractometer, Co-Kα radiation) and analyzed by Rietveld refinement using the FullProf Suite software package, including parameters such as zero point correction, scale factor, lattice constants, Lorentzian crystallite size parameters Y and SZ, and preferred orientations. The XRD patterns of the 3 precursor samples are shown in (FIG. 3 ). A Thompson-Cox-Hastings pseudo-Voigt function was used to describe the peak profile. Rietveld refinement retrieved a composition of the three samples. From this, the amount of six-line ferrihydrite (SLF) present in the non-magnetic precursor is approximately 15, 38 and 30% for SLF-100, SLF-150 and SLF-200 respectively. In the present analysis, the SLF phase was refined based on the Dritts model. SLF-100 showed poor crystallinity when compared with that of SLF-150 and SLF-200 as a consequence of the lower hydrothermal temperature used in the reaction. Rietveld refinement of the as-synthesized samples result in crystallites with platelet like shape, and an average A-length of 11 nm compared to C-length of 5.5 nm can be extracted.

Transmission electron microscopy (TEM) and spatially resolved elemental analysis were recorded for SLF-150 and SLF-200 on a FEI TALOS F200A TEM microscope operating at 200 kV, for approximately 200 particles and analysed using the Gatan software. The TEM micrographs confirmed the presence of microscopic platelets present in the as-synthesized powers of SLF-150 and SLF-200, see FIG. 4 . Lognormal fit to the size extracted from the TEM images results in particle dimensions of A=23 nm and C=7 nm for 150° C., while the 200° C. gave dimensions of A=30 nm and C=8 nm.

Since these non-magnetic nano-crystallites are not interacting with each other by way of magnetism, the crystallites can easily align along their faces when optimum pressure is applied either in cold compaction or using a spark plasma sintering (SPS). The alignment can happen at room temperature, because no magnetic interaction needs to be broken. However, for the conversion into SrFe₁₂O₁₉ elevated temperatures are needed.

Example 2: Preparation and Structural Characterization of Non-Ferromagnetic Precursor Comprising Anisotropic Crystallites of Hematite (α-Fe₂O₃) for Subsequent Preparation of Strontium Hexaferrite Permanent Magnets

Hematite (α-Fe₂O₃) precursors having a platelet morphology can be synthesized via a wet chemical approach as described in the following. Other reagents known to a person skilled in the art may be substituted to produce similar hematite crystallite precursors.

Hematite Precursor Made from FeCl₃·6H₂O

A 60 mL aqueous solution of 2 M of FeCl₃·6H₂O, was added dropwise to a 60 mL, 8 M NaOH solution whilst stirring, resulting in a dark red precipitate forming upon addition. The precipitate solution was transferred to a Teflon-lined stainless-steel autoclave, then heated at 160° C. for 2 hours. Once cooled the precipitate was washed using deionised water and centrifugated until the supernatant was pH 7. It was finally washed once with ethanol, placed in drying oven at 85° C. until dry, then ground with a pestle and mortar. The thus obtained precursors were further utilized in Examples 8 and 10.

The precursors were examined by X-ray powder diffraction (Rigaku SmartLab diffractometer, Co-Kα radiation) and analyzed by Rietveld refinement using the FullProf Suite software package, including parameters such as zero point correction, scale factor, lattice constants, Lorentzian crystallite size parameters Y and SZ, and preferred orientations. The XRD patterns of the 160° C. precursor is shown in FIG. 5 . A Thompson-Cox-Hastings pseudo-Voigt function was used to describe the peak profile.

The particle morphology analysis with TEM revealed hexagonal platelets with A-sizes in the order of 1-2 μm shown in FIG. 6 . The hexagonal platelets of hematite are either oriented with the platelet plane parallel to the view (light plate shape) or perpendicular (dark elongated shape). The observed light needles are goethite (α-FeOOH).

Example 3: Preparation and Structural Characterization of Non-Ferromagnetic Precursor Comprising Anisotropic Crystallites of Goethite (α-FeOOH) for Subsequent Preparation of Strontium Hexaferrite Permanent Magnets Goethite (α-FeOOH) Precursor Made from Fe(NO₃)₃·9H₂O

A 40 mL aqueous solution of 1 M of Fe(NO₃)₃·9H₂O was made and 8 M NaOH solutionwas added dropwise to obtained an [OH⁻]/[NO₃ ⁻] ratio of 1.33, resulting in a dark red precipitate forming upon addition of NaOH. The precipitate solution was allowed to stir for one hour. The precipitate solution was transferred to a Teflon-lined stainless steel autoclave. The pH was maintained at 11. The autoclave was heated at 100° C. for 10 hours. Once cooled the precipitate was washed using deionised water and centrifuged until the supernatant was pH 7. It was then washed once with ethanol, placed in drying at 85° C. until dry, then ground with pestle and mortar. The thus obtained precursors were further utilized in Example 10.

The precursors were examined by X-Ray powder diffraction (Rigaku Smart Lab Diffractometer, Co-Ka radiation) and analysed by Reitveld refinement using FullProf suite software package, including parameters such as zero point correction, scale factor, lattice constants, Lorentzian crystallite size parameters Y and SZ and preferred orientations. The XRD patterns of the 100° C. precursor is shown in FIG. 7 . A Thomas-Cox-Hastings pseudo-Voigt function was used to describe the peak profile. A TEM image of the goethite sample is shown in FIG. 8 , clearly revealing the needle-like morphology of the crystallites

Example 4: Preparation and Structural Characterisation of Aligned Magnetic M-Type Strontium Hexaferrite Using Non-Ferromagnetic Strontium Hexaferrite Precursor of Platelet Shaped Six-Line Ferrihydrite (SLF) and Spark Plasma Sintering (SPS).

The non-magnetic precursors prepared according to Example 1 were compacted into bulk strontium hexaferrite magnets using spark plasms sintering (SPS). 0.8 g of the precursor powder was weighed and placed in a graphite die of 12.6 mm inner diameter and enclosed between two graphite punches. Graphite paper (˜0.2 μm) was placed between the powders and the graphite die and between the die and the upper and lower punch. The die was subsequently inserted in a vacuum chamber of a SPS Synthex Inc. 1500 model, Dr. Sinter Lab series spark plasma sintering system. In the chamber, a uniaxial pressure was applied to the punches while a pulsed dc current was passed through the die, sintering the powders contained within. A maximum temperature of 750° C. and maximum pressure of 100 MPa were applied during the sintering process, which was completed after 8 minutes. The die was freely cooled before the sintered pellet was extracted. Finally, the graphite paper that adhered to the pellet was removed by polishing. The thus produced pellet, consisting of aligned M-type strontium hexaferrite permanent magnets, having a diameter of 12.6 mm and a thickness of ˜1 mm. The SPS pellets were named SPS-1, SPS-2 and SPS-3 corresponding to the SLF-100, SLF-150 and SLF-200 precursor samples respectively.

The SPS pellets were subjected to X-ray diffraction analysis using the same Rietveld parameters presented in Example 1. The powder X-ray diffractograms collected on the obtained SPS pellets reveal a major suppression of the Bragg reflections with (hk0). This selective Bragg reflection suppression is due to the crystallographic orientation of the crystallites within the sample, this is also referred to as crystallographic preferred orientation or texture and it is due to the anisotropic shape of the crystallites. The anisotropy effect is especially pronounced in the SPS-3 sample, where almost a complete suppression is observed for any reflection other than (00l) as shown in FIG. 9 . The preferred orientation was implemented in the structural modelling of the powder diffraction data using the March-Dollase multiaxial function. According to the Rietveld refinements, SPS-3 exhibits the largest degree of preferred orientation while SPS-1 has the lowest degree of preferred orientation. Other relevant physical properties are summarized further below in Table 1.

Example 5: Preparation and Structural Characterisation of Aligned Magnetic M-Type Strontium Hexaferrite Using Non-Ferromagnetic Strontium Hexaferrite Precursor of Platelet Shaped Six-Line Ferrihydrite (SLF) and Cold Compaction Followed by Calcination

The precursor powders described in example 1 were subjected to conventional co-compaction followed by calcination of the compacted pellets. 2 pellets of 0.15 g for each of the precursor powders SLF-100, SLF-150, and SLF-200 were prepared for sintering at 750° C., 900° C., and 1050° C. The pellets were compacted with similar conditions of 2 tonnes of pressure for five minutes corresponding to 700 MPa. After compaction to dense pellets, the samples were sintered at 750° C., 900° C., and 1050° C. for 2 hours. During the sintering, the samples were held in an Al₂O₃ crucible. The compacted and sintered pellets (identified as T_(Hyd)(100), T_(Hyd)(150), and T_(Hyd)(200) in reference to the precursor) were subjected to X-ray diffraction analysis employing the Rietveld analysis parameters as presented in Example 1, see FIG. 10 . Relevant physical properties are summarized further below in Table 1.

Example 6: Characterization of Magnetic Properties in Aligned M-Type Strontium Hexaferrite Magnets Obtained from Using Non-Ferromagnetic Strontium Hexaferrite Precursor of Platelet Shaped Six-Line Ferrihydrite (SLF) and Spark Plasma Sintering (SPS).

Magnetic properties of the SPS pellets were measured using a Quantum Design Physical Properties Measurement System (PPMS) equipped with a vibrating sample magnetometer (VSM). For the measurements, the SPS pellet was placed in a tubular brass sample holder and held between two quartz rods. Room temperature magnetic hysteresis loop measured on the SPS compacted pellets are presented in FIG. 11 nd was measured using standard experimental settings well-known to a person of skill in the art.

The alignment of the crystallites in a magnet can also be evaluated indirectly in the magnetism of said magnet based on the hysteretic squareness ratio defined by M_(r)/M_(s). The Stoner Wohlfrath model states that an ideally aligned magnet gives a ratio equal to unity, while it decreases to 0.5 for completely randomly oriented crystallites. Table 2 found further below summarizes this and other key properties of the presented samples.

Example 7: Characterization of Magnetic Properties in Aligned M-Type Strontium Hexaferrite Magnets Obtained from Using Non-Ferromagnetic Strontium Hexaferrite Precursor of Platelet Shaped Six-Line Ferrihydrite (SLF) and Cold Compaction Followed by Calcination.

In a similar manner to Example 6, VSM magnetic measurements were conducted on the permanent magnets obtained according to Example 5 (T_(Hyd)(100), T_(Hyd)(150), and T_(Hyd)(200)) to extract the magnetic hysteresis loops (FIG. 12 ). Extracted physical properties are summarized below in Table 2.

TABLE 1 Overview of structural and magnetic properties of strontium hexaferrite permanent magnet prepared from the SLF-precursors of Example 1 using cold compaction or SPS compaction (Example 6). Sintering Pressure G₁ 008/ H_(C) BH_(max) Sample Temp (° C.) (MPa) pref. (008 + 110) M_(r)/M_(s) (kA/m) (kJ/m³) T_(Hyd)(100) 750 700 0.907 0.322 0.563 502 9 900 700 0.752 0.508 0.651 199 11 T_(Hyd)(150) 750 700 0.832 0.416 0.639 511 11 900 700 0.845 0.404 0.610 509 12 1050 700 0.665 0.681 0.756 78 9.28 T_(Hyd)(200) 750 700 0.737 0.566 0.654 470 12 900 700 0.537 0.835 0.747 279 21 1050 700 0.494 0.906 0.806 100 18 SPS-1 750 100 0.694 0.623 0.659 474 11 SPS-2 750 100 0.387 0.951 0.898 265 27 SPS-3 750 100 0.322 0.981 0.926 247 33

The parameter G₁ stems from the Rietveld refinement and gives a qualitative measure for the preferred orientation in the sample. The lower the number the higher the preferred orientation. The number can vary between 1 and 0, where 1 is a randomly oriented sample and 0 is close to a single crystal. Another method for looking at preferred orientation is to look at the integrated area of some of the characterizing peaks found in the diffraction patterns, e.g. the (110) and (008) peaks. Here (008) gives information on crystallites being oriented parallel with the wanted direction, while (110) is crystal planes perpendicular to the wanted direction. The following index is used (008)/[(110)+(008)] to quantify the alignment and should preferably be between 1 and 0.5 with 1 representing the most aligned sample.

M_(r)/M_(s) ratio from Table 1 shows the squareness ratio for the differently prepared samples. For all the presented magnets found in Table 2, it is evident that the temperature used in producing the non-magnetic anisotropic precursor has a direct influence on the hysteretic squareness ratio, with a higher synthesis temperature resulting in a squareness ratio closer to unity. This in turn shows that sample alignment can be controlled by the synthesis temperature, provided that initial nanoparticles synthesized are thin platelets or needles.

The (BH)_(max) of all samples were analyzed and it was found that SPS-3 showed the highest value of (BH)_(max) with 33(4) kJ/m³, followed by SPS-2 (27 kJ/m³) and T_(Hyd)(200) (21 kJ/m³). These samples also show the highest degree of crystallite alignment as evidenced by G₁ and [008/(008+110)] value.

The magnetic properties as evaluated by magnetic hysteresis showed an enhanced maximum energy product of the aligned M-type strontium hexaferrite obtained using anisotropic non-magnet precursors of (BH)_(max)=33 kJ/m³ compared to those found in commercially available La—Co free hexaferrites, obtained by dry processing [(BH)_(max)=26-29 kJ/m³].

Example 8: Preparation and Structural Characterisation of Aligned Magnetic M-Type Strontium Hexaferrite Using Non-Ferromagnetic Strontium Hexaferrite Precursor of Platelet Shaped Hematite (α-Fe₂O₃) and Cold Compaction Followed by Calcination

Different ways of mixing the precursor powder from Example 2 with SrCO₃ and Sr(OH)₂ was tested. Different pressures was also applied in the cold compaction to check the effect on the alignment.

Dry Mixing

A precursor from Example 2 (α-Fe₂O₃ 70 wt. % and α-FeOOH 30 wt. %) 4.003 g (50.1 mmol) was weighed off and hand mixed in an agate pestle and mortar with 0.619 g (4.18 mmol) of SrCO₃ for 15 minutes. A mixing ratio of 1:10 molar ratio of Sr:Fe was used.

Wet Mixing

To avoid the grinding having an effect of the shape of the crystallites, the precursor material in Example 2 was wet mixed with Sr(OH)₂. A mass of 0.476 g (3.91 mmol) of anhydrous Sr(OH)₂ was dissolved in 30 mL deionised water until a homogeneous solution was achieved at 85° C. 3.750g (47.0 mmol) of precursor from Example 2 was added and stirred continuously for 45 mins at 85° C. The resultant slurry was poured onto a petri dish and was dried on a hot plate at 35° C. overnight. The dried mixture was scraped out and ground in a pestle and mortar for 2 minutes. A mixing ratio of 1:10 molar ratio of Sr:Fe was used.

Cold Compaction and Calcination

Four pellets of 0.4 g were prepared, two of the wet mixed (WM) and two of the dry mixed (DM). All pellets were uniaxial cold pressed in a 12.6 mm diameter pressing die. The low pressure pellets was made were made at 2.5 tonnes/cm² of pressure for 5 minutes corresponding to a pressure of 220 MPa. The dry mixed and wet mixed pellets were named DM 220 MPa and WM 220 MPa respectively. High pressure pellets were pressed at 10 tonnes/cm² of pressure for 5 minutes corresponding to 870 MPa. The dry mixed and wet mixed pellets named DM 870 MPa and WM 870 MPa respectively. After compaction to dense pellets all samples were calcined at 1100° C. for 2 hours. During the calcination the samples were held in an Al₂O₃ crucible.

After pressing and calcination, the pellets were subjected to X-ray diffraction analysis using the same Rietveld parameters presented in Example 4. The powder X-ray patterns collected on the as-obtained calcined pellets reveal a major suppression of the Bragg reflections with (hk0). FIG. 13 shows the powder diffraction pattern, where the preferred orientation was refined using the March-Dollase function as already explained. The XRD data reveal a clear preferred orientation of the sample. A summary of relevant physical properties is found further below in Table 3.

Example 9: Characterization of Magnetic Properties in Aligned M-Type Strontium Hexaferrite Magnets Obtained from Using Non-Ferromagnetic Strontium Hexaferrite Precursor of Platelet Shaped Hematite (α-Fe₂O₃) and Cold Compaction Followed by Calcination

In a similar manner to Example 6, VSM magnetic measurements were conducted on the permanent magnets obtained according to Example 8 (DM 220 MPa, DM 870 MPa, WM 220 MPa, and WM 870 MPa)) to extract the magnetic hysteresis loops (FIG. 14 ).

Extracted physical properties are summarized below in Table 3.

TABLE 2 Overview of structural and magnetic properties of strontium hexaferrite permanent magnet prepared from the hematite-precursors of Example 2 using cold compaction and calcination (Example 8). Pressure G₁ H_(c) BH_(Max) Sample (MPa) pref M_(r)/M_(s) (kAm⁻¹) (kJm⁻³) Random orientation 0.98 0.54 297 11(2) Dry mixed 220 0.59 0.71 154 15(2) Dry mixed 870 0.53 0.74 122 15(2) Wet mixed 220 0.64 0.70 225 18(2) Wet mixed 870 0.54 0.75 185 21(2)

Table 3 illustrates the possibility and potential of producing rare-earth-free permanent magnets retaining a substantial maximum energy product from anisotropic non-magnetic precursors in a simple two-step process combining cold compaction and subsequent calcination. Such a simple two-step process is readily scalable to large production facilities due to its cheap costs and easy handling.

Example 10: Preparation and Structural Characterisation of Aligned Magnetic M-Type Strontium Hexaferrite Using Non-Ferromagnetic Strontium Hexaferrite Precursor Mixture of Platelet Shaped Hematite (α-Fe₂O₃) and of Needles Shaped Goethite (α-FeOOH) and Cold Compaction Followed by Calcination

Different ratios of hematite and goethite was mixed with corresponding amounts of SrCO₃. The hematite and goethite was prepared separately as in Example 2 and 3. The three powders were mixed as in Example 8 dry mixing.

Five pellets of ˜0.4 g were prepared, with the following hematite and goethite ratios 100% hematite, 75% hematite and 25% goethite, 50% hematite and 50% goethite, 25% hematite and 75% goethite, and finally 100% goethite. All pellets were uniaxial cold pressed in a 6 mm diameter pressing die. Applying a pressure of 10 tonnes/cm² of pressure for 5 minutes corresponding to 870 MPa. The samples were named (100% /0% hematite/goethite, 75%/25% hematite/goethite, 50%/50% hematite/goethite, 25%/75% hematite/goethite, 0%/100% hematite/goethite). After compaction to dense pellets all samples were calcined at 1100° C. for 2 hours. During the calcination the samples were held in an Al₂O₃ crucible.

Example 11: Characterization of Magnetic Properties in Aligned M-Type Strontium Hexaferrite Magnets Obtained from Using Non-Ferromagnetic Strontium Hexaferrite Precursor Mixture of Platelet Shaped Hematite (α-Fe₂O₃) and of Needles Shaped Goethite (α-FeOOH) and Cold Compaction Followed by Calcination

In a similar manner to Example 6, VSM magnetic measurements were conducted on the permanent magnets obtained according to Example 10 (100%/0% hematite/goethite, 75%/25% hematite/goethite, 50%/50% hematite/goethite, 25%/75% hematite / goethite, 0%/100% hematite/goethite). Extracted physical properties are summarized below in Table 4.

TABLE 4 Overview of structural and magnetic properties of strontium hexaferrite permanent magnet prepared from the hematite-precursors of Example 2 and goethite precursor of Example 3 using cold compaction at 870 MPa and calcination at 1100° C. for 2 hours. Hematite/ G₁ 008/ M_(r) M_(s) H_(C) BH_(max) Geothite pref. (008 + 110) Am²/kg Am²/kg M_(r)/M_(s) (kA/m) (kJ/m³) 100%/0%  0.61 0.72 51.8 74.1 0.70 208 21 75%/25% 0.61 0.74 51.2 74.3 0.70 181 19 50%/50% 0.58 0.80 51.9 74.0 0.70 202 20 25%/75% 0.50 0.88 54.6 73.0 0.75 174 21  0%/100% 0.43 0.94 59.7 72.3 0.80 157 22

Table 4 illustrates the possibility and potential of producing rare-earth-free permanent magnets retaining a substantial maximum energy product from anisotropic non-magnetic precursors in a simple two-step process combining cold compaction and subsequent calcination. Such a simple two-step process is readily scalable to large production facilities due to its cheap costs and easy handling.

ITEMS 1

-   -   1. A non-ferromagnetic precursor with a concentration of more         than 15% by weight of anisotropic crystalline materials of the         group consisting of six-line ferrihydrite (SLF), +-Fe₂O₃, and/or         α-FeOOH, each with an average aspect ratio A/C≥2, a size C         ranging from 2-200 nm, and a size A ranging from 4-2000 nm.     -   2. The precursor according to item 1, wherein said concentration         of anisotropic crystalline materials makes up 100% by weight,         such as 15-95% by weight.     -   3. The precursor according to any of the preceding items,         wherein said concentration of anisotropic crystalline materials         makes up 25 to 75% by weight.     -   4. The precursor according to any of items 1-3, wherein said         anisotropic crystalline material is six-line ferrihydrite (SLF),     -   5. The precursor according to any of items 1-3, wherein said         anisotropic crystalline material is α-Fe₂O₃.     -   6. The precursor according to any of items 1-3, wherein said         anisotropic crystalline material is α-FeOOH.     -   7. The precursor of any of the preceding items, further         comprising one or more sources of metals such as Calcium (Ca),         Strontium (Sr), Barium (Ba), Magnesium (Mg), Manganese (Mn),         Iron (Fe), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), and         Lanthanum (La).     -   8. The non-ferromagnetic precursor of any of the preceding         items, for use in formation of a strontium hexaferrite permanent         magnet.     -   9. A method of producing a non-ferromagnetic precursor,         comprising the steps of:         -   a. mixing salts of Fe³⁺ with a strong alkaline solution to             form a gel,         -   b. transferring said gel to an autoclave, and sealing said             autoclave,         -   c. placing said autoclave at a temperature of equal to or             less than 200° C. for more than 1 hour under autogenous             pressure, and         -   d. isolating the formed anisotropic crystalline non-magnetic             precursor material.     -   10. The method according to item 9, wherein step a. may further         comprise the addition of a source of a divalent metal such         Calcium (Ca), Strontium (Sr), Barium (Ba), Magnesium (Mg),         Manganese (Mn), Iron (Fe), Cobalt (Co), Nickel (Ni), Copper         (Cu), and Zinc (Zn).     -   11. A method of producing a strontium hexaferrite permanent         magnet comprising the steps of:         -   a. providing a non-ferromagnetic precursor according to any             of items 1-7;         -   b. compacting said precursor at a temperature between             700-1000° C. by spark plasma sintering (SPS) in the absence             of any applied magnetic field, thereby inducing a phase             change, and         -   c. isolating the thus formed M-type permanent magnet.     -   12. A method of producing a strontium hexaferrite permanent         magnet comprising the steps of:         -   a. providing a non-ferromagnetic precursor according to any             of items 1-7;         -   b. compacting said precursor by the application of pressure         -   c. calcining said compacted precursor at a temperature             between 700-1220° C. in the absence of any applied magnetic             field, thereby inducing a phase change, and         -   d. isolating the M-type permanent magnet.     -   13. The method of producing a strontium hexaferrite permanent         according to any of items 11-12, wherein the anisotropic         crystalline material of said precursor is largely α-Fe₂O₃.     -   14. The method of producing a strontium hexaferrite permanent         according to any of items 11-12, wherein the anisotropic         crystalline material of said precursor is largely six-line         ferrihydrite (SLF).     -   15. The method of producing a strontium hexaferrite permanent         according to any of items 11-12, wherein the anisotropic         crystalline material of said precursor is largely α-FeOOH.     -   16. A strontium hexaferrite permanent magnet comprising highly         aligned strontium hexaferrite, characterized by its most intense         Bragg reflections being the (006), (008), (107) and (0014)         reflections, and wherein the (008)/[(110+008)] integrated         intensity ratio is at least 0.5 as obtained by X-ray powder         diffraction using Co-Kα radiation.     -   17. The strontium hexaferrite permanent magnet according to item         16, further comprising pronounced Bragg reflections along the         (00l) reflection, as evidenced by powder X-ray diffraction         obtained using Co-Kα radiation.     -   18. The strontium hexaferrite permanent magnet according to any         of items 16-17, further comprising an X-ray powder diffraction         pattern with characteristic peaks expressed in 2-theta angle (°)         for (006) at 2θ=26.9°±0.2°, (110) at 2θ=35.4°±0.2°, (008) at         2θ=36.3°±0.2°, (107) at 2θ=37.7°±0.2° and (0014) at         2θ=65.8°±0.2° as obtained using Co-Kα radiation.     -   19. The strontium hexaferrite permanent magnet according to any         of items 16-18, with a powder X-ray pattern substantially         similar to FIG. 9 .     -   20. The strontium hexaferrite permanent magnet according to any         of items 16-19, further comprising a hysterisis squareness ratio         (M_(R)/M_(s)) which is between 0.65 and 1.0, such as between         0.70 and 1.0, such as between 0.75 and 1.0, such as between 0.80         and 1.0, such as between 0.85 and 1.0, such as between 0.95 and         1.0.     -   21. The strontium hexaferrite permanent magnet according to any         of items 16-20, further comprising a hysteretic squareness ratio         (M_(r)/M_(s)) is between 0.85 and 1.0, such as between 0.95 and         1.0.     -   22. Use of a strontium hexaferrite permanent magnet according to         any of the preceding items as a magnetic component in a device.     -   23. The use according to the preceding item wherein said device         is any one of:         -   a. storage devices,         -   b. generators,         -   c. stators in electric motors and/or electric engines,         -   d. audio devices,         -   e. magnetic imaging scanners,         -   f. magnetic brakes,         -   g. linear motors,         -   h. electrodynamic bearings, or         -   i. magnetic toys.

ITEMS 2

-   -   1. A non-ferromagnetic precursor with a concentration of more         than 15% by weight of anisotropic crystalline materials of the         group consisting of six-line ferrihydrite (SLF), α-Fe₂O₃, and/or         α-FeOOH, each with an average aspect ratio A/C≥2, a size C         ranging from 2-200 nm, and a size A ranging from 4-2000 nm.     -   2. The precursor according to item 1, wherein said concentration         of anisotropic crystalline materials makes up 100% by weight,         such as 15-95% by weight.     -   3. The precursor according to any of the preceding items ,         wherein said concentration of anisotropic crystalline materials         makes up 25 to 75% by weight.     -   4. The precursor of any of the preceding items, further         comprising one or more sources of metals such as Calcium (Ca),         Strontium (Sr), Barium (Ba), Magnesium (Mg), Manganese (Mn),         Iron (Fe), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), and         Lanthanum (La).     -   5. The non-ferromagnetic precursor of any of the preceding         items, for use in formation of a strontium hexaferrite permanent         magnet.     -   6. A method of producing a non-ferromagnetic precursor,         comprising the steps of:         -   a. mixing salts of Fe³⁺ with a strong alkaline solution to             form a gel,         -   b. transferring said gel to an autoclave, and sealing said             autoclave,         -   c. placing said autoclave at a temperature of equal to or             less than 200° C. for more than 1 hour under autogenous             pressure, and         -   d. isolating the formed anisotropic crystalline non-magnetic             precursor material.     -   7. The method according to items 6, wherein step a. may further         comprise the addition of a source of a divalent metal such         Calcium (Ca), Strontium (Sr), Barium (Ba), Magnesium (Mg),         Manganese (Mn), Iron (Fe), Cobalt (Co), Nickel (Ni), Copper         (Cu), and Zinc (Zn).     -   8. A method of producing a strontium hexaferrite permanent         magnet comprising the steps of:         -   a. providing a non-ferromagnetic precursor according to any             of items 1-4;         -   b. compacting said precursor at a temperature between             700-1000° C. by spark plasma sintering (SPS) in the absence             of any applied magnetic field, thereby inducing a phase             change, and         -   c. isolating the thus formed M-type permanent magnet.     -   9. A method of producing a strontium hexaferrite permanent         magnet comprising the steps of:         -   a. providing a non-ferromagnetic precursor according to any             of items 1-4;         -   b. compacting said precursor by the application of pressure         -   c. calcining said compacted precursor at a temperature             between 700-1220° C. in the absence of any applied magnetic             field, thereby inducing a phase change, and         -   d. isolating the M-type permanent magnet.     -   10. A strontium hexaferrite permanent magnet comprising highly         aligned strontium hexaferrite, characterized by its most intense         Bragg reflections being the (006), (008), (107) and (0014)         reflections, and wherein the (008)/[(110+008)] integrated         intensity ratio is at least 0.5 as obtained by X-ray powder         diffraction using Co-Kα radiation.     -   11. The strontium hexaferrite permanent magnet according to item         10, further comprising pronounced Bragg reflections along the         (00l) reflection, as evidenced by powder X-ray diffraction         obtained using Co-Kα radiation.     -   12. The strontium hexaferrite permanent magnet according to any         of items 10-11, further comprising an X-ray powder diffraction         pattern with characteristic peaks expressed in 2-theta angle (°)         for (006) at 2θ=26.9°±0.2°, (110) at 2θ=35.4°±0.2°, (008) at         2θ=36.3°±0.2°, (107) at 2θ=37.7°±0.2° and (0014) at         2θ=65.8°±0.2° as obtained using Co-Kα radiation.     -   13. The strontium hexaferrite permanent magnet according to any         of items 10-12, further comprising a hysterisis squareness ratio         (M_(R)/M_(s)) which is between 0.65 and 1.0, such as between         0.70 and 1.0, such as between 0.75 and 1.0, such as between 0.80         and 1.0, such as between 0.85 and 1.0, such as between 0.95 and         1.0.     -   14. The strontium hexaferrite permanent magnet according to any         of items 10-13, further comprising a hysteretic squareness ratio         (M_(r)/M_(s)) is between 0.85 and 1.0, such as between 0.95 and         1.0.     -   15. Use of a strontium hexaferrite permanent magnet according to         any of the preceding items as a magnetic component in a device. 

1. A non-ferromagnetic strontium hexaferrite precursor with a concentration of more than 15% by weight of anisotropic crystalline materials of the group consisting of six-line ferrihydrite (SLF), α-Fe₂O₃, and/or α-FeOOH, each with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm, wherein the non-ferromagnetic strontium hexaferrite precursor further comprises one or more sources of metals such as Strontium (Sr), Calcium (Ca), Barium (Ba), Magnesium (Mg), Manganese (Mn), Iron (Fe), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), and Lanthanum (La).
 2. The non-ferromagnetic strontium hexaferrite precursor according to claim 1, wherein said concentration of anisotropic crystalline materials makes up 100% by weight, such as 15-95% by weight.
 3. The non-ferromagnetic strontium hexaferrite precursor according to any one of claims 1 to 2, wherein said concentration of anisotropic crystalline materials makes up 25 to 75% by weight.
 4. The non-ferromagnetic strontium hexaferrite precursor of any one of claims 1 to 3, wherein the metal is strontium (Sr).
 5. Use of the non-ferromagnetic strontium hexaferrite precursor according to any one of claims 1 to 4, for forming a strontium hexaferrite permanent magnet.
 6. A method of producing a non-ferromagnetic strontium hexaferrite precursor comprising six-line ferrihydrite (SLF), the method comprising the steps of: a. mixing salts of Fe³⁺ and Sr²⁺ with a strong alkaline solution to form a gel, b. transferring said gel to an autoclave, and sealing said autoclave, c. placing said autoclave at a temperature ranging from 200-100° C. for more than 1 hour under autogenous pressure, and d. isolating the formed anisotropic crystalline non-ferromagnetic strontium hexaferrite precursor material comprising six-line ferrihydrite (SLF).
 7. The method according to claim 6, wherein the salts of Fe³⁺ and Sr²⁺ are mixed in a Fe/Sr ratio is about
 8. 8. The method according to any one of claims 6 to 7, wherein the reaction time is about 5 hours.
 9. A non-ferromagnetic strontium hexaferrite precursor material comprising at least approximately 15wt % six-line ferrihydrite (SLF) crystallites having with a platelet or platelet-like morphology with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm obtainable by the method according to any one of claims 6 to
 8. 10. A method of producing a non-ferromagnetic strontium hexaferrite precursor comprising Hematite (α-Fe₂O₃), the method comprising the steps of: a. mixing salts of Fe³⁺ with a strong alkaline solution to form a mixture comprising a dark red precipitate; b. transferring said mixture to an autoclave, and sealing said autoclave; c. placing said autoclave at a temperature of 200-100° C. for more than 1 hour under autogenous pressure; d. isolating the formed anisotropic crystalline non-magnetic precursor material; and e. adding a source of strontium (Sr) to the isolated material to obtain the non-ferromagnetic strontium hexaferrite precursor comprising Hematite (α-Fe₂O₃).
 11. The method according to claim 10, wherein the isolation step d comprises washing the formed anisotropic crystalline non-magnetic precursor material with water to neutral pH (pH of 7), followed by washing with ethanol and drying at 85° C. until dry.
 12. The method according to any one of claims 10 to 11, wherein the temperature is about 160° C.
 13. The method according to any one of claims 10 to 12, wherein the reaction time under autogenous pressure is about 2 hours.
 14. The method according to any one of claims 10 to 13, wherein the metal to base ratio Fe/OH is
 4. 15. The method according to any one of claims 10 to 14, wherein the source of strontium is added to obtain an Fe/Sr molar ratio of
 12. 16. A non-ferromagnetic strontium hexaferrite precursor material comprising at least approximately 15 wt % Hematite (α-Fe₂O₃) crystallites having with a platelet or platelet-like morphology with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm obtainable by the method according to any one of claims 10 to
 15. 17. A method of producing a non-ferromagnetic strontium hexaferrite precursor comprising Goethite (α-FeOOH), the method comprising the steps of: a. mixing salts of Fe³⁺ with a strong alkaline solution to form a mixture comprising a dark red precipitate; b. transferring said mixture to an autoclave, and sealing said autoclave; c. placing said autoclave at a temperature of 200-100° C. for more than 1 hour under autogenous pressure; d. isolating the formed anisotropic crystalline non-magnetic precursor material; and e. adding a source of Strontium (Sr) to the isolated material to obtain the non-ferromagnetic strontium hexaferrite precursor comprising Goethite (α-FeOOH).
 18. The method according to claim 17, wherein the isolation step d comprises washing the formed anisotropic crystalline non-magnetic precursor material with water to neutral pH (pH of 7), followed by washing with ethanol and drying at 85° C. until dry.
 19. The method according to any one of claims 17 to 18, wherein the reaction temperature is about 100° C.
 20. The method according to any one of claims 17 to 19, wherein the reaction time under autogenous pressure is about 10 hours.
 21. The method according to any one of claims 17 to 20, wherein the step b. comprises said mixture having a pH of about
 11. 22. The method according to any one of claims 17 to 21, wherein the source of strontium is added to obtain an Fe/Sr molar ratio of
 12. 23. A non-ferromagnetic strontium hexaferrite precursor material comprising at least approximately 15 wt % Goethite (α-FeOOH) crystallites having with a needle or needle-like morphology with an average aspect ratio A/C≥2, a size C ranging from 2-200 nm, and a size A ranging from 4-2000 nm obtainable by the method according to any one of claims 17 to
 22. 24. A method of producing a strontium hexaferrite permanent magnet comprising the steps of: a. providing a non-ferromagnetic strontium hexaferrite precursor according to any of claims 1 to 4, 9, 16, and 23; b. compacting said precursor at a temperature between 700-1000° C. by spark plasma sintering (SPS) in the absence of any applied magnetic field, thereby inducing a phase change, and c. isolating the thus formed strontium hexaferrite permanent magnet.
 25. A method of producing a strontium hexaferrite permanent magnet comprising the steps of: a. providing a non-ferromagnetic strontium hexaferrite precursor according to any of claims 1 to 4, 9, 16, and 23; b. compacting said precursor by the application of pressure c. calcining said compacted precursor at a temperature between 700-1220° C. in the absence of any applied magnetic field, thereby inducing a phase change, and d. isolating the thus formed strontium hexaferrite permanent magnet.
 26. A strontium hexaferrite permanent magnet comprising highly aligned strontium hexaferrite, characterized by its most intense Bragg reflections being the (006), (008), (107) and (0014) reflections, and wherein the (008)/[(110+008)] integrated intensity ratio is at least 0.5 as obtained by X-ray powder diffraction using Co-Kα radiation.
 27. The strontium hexaferrite permanent magnet according to claim 26, further comprising pronounced Bragg reflections along the (00l) reflection, as evidenced by powder X-ray diffraction obtained using Co-Kα radiation.
 28. The strontium hexaferrite permanent magnet according to any of claims 26 to 27, characterized by comprising an X-ray powder diffraction pattern with characteristic peaks expressed in 2-theta angle (°) for (006) at 2θ=26.9°±0.2°, (110) at 2θ=35.4°±0.2°, (008) at 2θ=36.3°±0.2°, (107) at 2θ=37.7°±0.2° and (0014) at 2θ=65.8°±0.2° as obtained using Co-Kα radiation.
 29. The strontium hexaferrite permanent magnet according to any of claims 26 to 15 28, characterized by comprising a hysterisis squareness ratio (M_(r)/M_(s)) which is between 0.65 and 1.0, such as between 0.70 and 1.0, such as between 0.75 and 1.0, such as between 0.80 and 1.0, such as between 0.85 and 1.0, such as between 0.95 and 1.0.
 30. The strontium hexaferrite permanent magnet according to any of claims 26 to 29, characterized by comprising a hysteretic squareness ratio (M_(r)/M_(s)) is between 0.85 and 1.0, such as between 0.95 and 1.0.
 31. A strontium hexaferrite permanent magnet comprising strontium hexaferrite according to any one of claims 26 to 30, obtainable by the method according to any one of claims 24 to
 25. 32. Use of a strontium hexaferrite permanent magnet according to any one of claims 26 to 31 as a magnetic component in a device. 